Multi-responsive amphiphilic gold nanoparticles (AuNPs) protected by poly(ether amine) (PEA).
نویسندگان
چکیده
Multi-responsive amphiphilic gold nanoparticles (AuNPs) protected by graft poly(ether amine) have been prepared simply by a one-pot photochemical synthesis in the presence of thio-graft poly(ether amine) (gPEA-SH) and the mechanism was studied in detail.
منابع مشابه
C2jm31273e 13365..13373
Gold clusters with controlled sizes have been prepared by controlled self-assembly of citrate stabilized gold nanoparticles (AuNPs) with temperature-responsive luminescent amphiphilic dendrimers (Den 40) of oligo(p-phenylene vinylene) core branches and oligo(ethylene oxide) terminal chains. The shape and size of the resultant gold clusters depend strongly on the molar ratio of Den 40 to AuNPs. ...
متن کاملEnhanced cellular uptake of amphiphilic gold nanoparticles with ester functionality.
Gold nanoparticles (AuNPs) coated with ester-headed or ether-headed PEG ligands were synthesized. Ester-headed AuNPs, but not ether-headed, were transferred from the organic phase (CH2Cl2) to the alkali aqueous phase, indicating that the hydrolysis of the ester moiety triggered the phase transfer of the AuNPs. We found that AuNPs with ester-headed ligands (ester-AuNPs) were internalized into He...
متن کاملSilica/titania sandwich-like mesoporous nanosheets embedded with metal nanoparticles templated by hyperbranched poly(ether amine) (hPEA).
We here demonstrated a novel square silica/titania mesoporous nanosheet which was prepared with hyperbranched poly(ether amine) nanosheets (hPEA-NSs) as a template. TEM and SEM images reveal that the obtained nanosheets possess a large aspect ratio with the average edge length of 1-2 μm and thickness of ~40 nm, respectively. Various metal nanoparticles such as gold, silver, and platinum can be ...
متن کاملTunable and reversible aggregation of poly(ethylene oxide-st-propylene oxide) grafted gold nanoparticles.
Two amino-terminated amphiphilic copolymers, M600 and M1000, with different ethylene oxide to propylene oxide EO/PO ratios, 1/9 and 19/3, respectively, were coupled by thioctic acid, which allows an excellent affinity with gold surface. Then, amphiphilic thermally responsive gold nanoparticles (AuNPs) were prepared either by ligands exchange on precursor gold nanoparticles or by direct reductio...
متن کاملResponsive hybrid nanosheets of hyperbranched poly(ether amine) as a 2D-platform for metal nanoparticles.
Hybrid nanosheets of hyperbranched poly(ether amine) are demonstrated as a novel 2D-platform for metal nanoparticles, which makes metal nanoparticles transfer reversibly between oil and water phases.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 43 شماره
صفحات -
تاریخ انتشار 2009